Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k−20°C < k4°C < k20°C < k35°C < k55°C. The activation energy (Ea) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL−1. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs. 相似文献
Fluorescent detection is a new spectroscopic measurement for ions sensing due to the advantages of real-time determination with high selectivity, accuracy, and low cost. However, chemosensors based on fluorescent detection are usually determined by absolute intensity from a monochromatic emission signal, which is easy to be fluctuated by the external environment, especially for Fe3+ detection in complex fluids. Herein, we rationally design a dual-emission Eu3+: CDs@ZIF-8 to construct a ratiometric fluorescent sensor with self-calibrating ability for Fe3+ determination. High efficient carbon dots (CDs) are embedded in europium ions (Eu3+)-doped MOF by simple stirring preparation at room temperature. The label-free ratiometric fluorescent probe (ICDs@ZIF-8/IEu) exhibits simultaneous blue and red emission under the same excitation at 365 nm. Remarkably, Eu3+: CDs@ZIF-8 displays the superiority of high selectivity to Fe3+, which shows ratiometric fluorescence characteristics (I0/I) in a range of 0-6 μmol\L with a low limit of detection (LOD) of 0.897 μmol\L. Besides, the CDs-MOF nanocomposite holds good aqueous dispersibility and low cytotoxicity, which shows great potential applications in medical aid including biological detection and clinical diagnosis. 相似文献
Suspension plasma spraying (SPS) as a potential technique to prepare thermal barrier coatings (TBCs) has been attracting more and more attention. However, most reports on SPS were carried out in the atmosphere. Given the unique features of in-flight particles and plasma jets under low pressure, the resulting coatings are expected to be different from those under atmospheric pressure. In this article, yttria-stabilized zirconia (YSZ) thermal barrier coatings were prepared using suspension plasma spraying under different environmental pressures. The results show that as the environmental pressure decreased, the column-like structural coating turned into a vertical crack segmented structure, as well as a dramatic decrease in surface roughness. More nanoparticle agglomerates were formed in the coating under lower environmental pressures. The real porosity of the coating increased with a decrease in environmental pressure. 相似文献
Water Resources Management - Precise and reliable monthly runoff prediction plays a vital role in the optimal management of water resources, but the nonstationarity and skewness of monthly runoff... 相似文献
The Muskingum-based (MK-based) distributions and their probability weighted moments (PWMs) have been used for frequency calculation of hydrological data that contain zero values. However, the performance of different MK-based distributions have not been compared and evaluated. Moreover, the partial L-moments (PLMs), which are used for analyzing censored samples, have not been used for frequency calculation of such hydrological data. To obtain the most effective method, this study compares and evaluates the performance of four MK-based distributions by fitting 64 monthly precipitation series and using the ordinary least square (OLS) criterion, Akaike information criterion (AIC), residual square sum criterion (RSS), and the Quasi-optimal Deterministic coefficient (QD). The distributions include ?exponential distribution combines with Dirac delta function (M-like), two-parameter gamma distribution (GA2) combines with Dirac delta function (DGA2), two-parameter generalized Pareto distribution combines with Dirac delta function (DGP2), and two-parameter Weibull distribution (WB2) combines with Dirac delta function (DWB2). The applicability of PLMs were also tested and PLMs of four traditional distributions, including GA2, WB2, generalized extreme value distribution (GEV) and three-parameter generalized Pareto distribution (GP3) were used in application. Results showed that the PLMs are feasible for frequency calculation of hydrological data with zeros. The DGP2 and GP3 are superior to the other MK-based distributions and traditional distributions, respectively. The DGP2 distribution is the optimal choice in most cases and is more universal than the other distributions.